Role of Multiplicity in Control System Design for a Methyl Acetate Reactive Distillation Column

نویسندگان

  • M. V. Pavan Kumar
  • Nitin Kaistha
چکیده

The impact of steady-state multiplicities on the control of a methyl acetate reactive distillation (RD) column is studied. It is shown that input multiplicity, where multiple input values give the same output, can lead to “wrong” control action, leading to poor robustness. A new metric, rangeability, is defined to quantify the severity of input multiplicity in a steady-state input-output (IO) relation. Rangeability can be used in conjunction with conventional sensitivity analysis for the design of robust control structures for RD systems. The design methodology is illustrated for the temperature based control of an industrial scale methyl acetate column. Results for a synthesized control structure shows that controlling the most sensitive reactive tray temperature can lead to poor robustness due to low rangeability resulting in “wrong” control action for large disturbances. Controlling a reactive tray temperature with acceptable sensitivity but larger rangeability gives better robustness. It is also shown that controlling the difference in the temperature of two suitably chosen reactive trays gives better robustness of the control structure due to improved rangeability. The article brings out the importance of IO relations in understanding the complex dynamic behavior of RD systems.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Reactive Distillation: Control Structure and Process Design for Robustness

Reactive Distillation (RD) is the combination of reaction and distillation in a single vessel (Backhaus, 1921). Over the past two decades, it has emerged as a promising alternative to conventional “reaction followed by separation” processes (Towler & Frey, 2002). The technology is attractive when the reactant-product component relative volatilities allow recycle of reactants into the reactive z...

متن کامل

Comparative control study of ideal and methyl acetate reactive distillation

The control of an ideal reactive distillation column is compared with that of a similar, but somewhat di2erent, real chemical system, the production of methyl acetate. Similarities and di2erences are observed. Three control structures are evaluated for both systems. A control structure with one internal composition controller and one temperature controller provides e2ective control of both syst...

متن کامل

Steady State Analysis for the Synthesis of Reactive Distillation Column Control Structures

The synthesis of effective control structures for reactive distillation (RD) columns through a systematic analysis of the steady state relationship between potential manipulated variables (inputs) and potential controlled variables (outputs) is demonstrated. The industrially important double feed RD columns for MTBE and methyl acetate production are used as examples. In order to regulate produc...

متن کامل

Conceptual Design of n-Butyl Acetate Synthesis Process by Reactive Distillation Using Residue Curve Maps

Residue curve maps are a powerful tool for the preliminary design of Reactive Distillation (RD). In this study, residue curve maps of the n-butyl acetate synthesis reaction were calculated based on the Langmuir–Hinshelwood–Hougen–Watson kinetic and UNIQUAC models to calculate the physical properties of the system. The results showed that the unstable node branch emerged from the n-butyl ace...

متن کامل

Transesterification Processes by Combination of Reactive Distillation and Pervaporation

The development of a reactive distillation process for the production of n-butyl acetate by transesterification of methyl acetate with n-butanol is presented. Thermodynamic aspects of the quaternary system n-butyl acetate – n-butanol – methyl acetate – methanol are discussed and UNIQUAC interaction parameters derived using the Dortmund Data Bank (DDB) are given. The reaction kinetics of the het...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2006